If you are unsure of if the system still has a Freon charge in it, you can remove one of the Shrader valve caps and gently probe the Shrader valve to see if any gas escapes when you depress the valve slightly. IF you get a "hiss", then there's an undetermined amount of gas still in the system.
An observed issue with an a/c shop using a recovery machine to evacuate the system is that using a R-134a recovery machine to recover non-R-134a will result in contamination of the existing R-134a in their machine. The recovery machine takes the oil gas out, cleans it, stores it for re-installation, adding any necessary gas from the machine's cannister of same. Only difference in the R-12 machine and a R-134a machine is the gas in them. So they operate the same, in that respect. End result of using a R-134a machine to remove R-12 is that you might have to pay for a new cannister of R-134a to replace the existing cannister that was contaminated by your suspected R-12. R-134a conversions usually have different service valves screwed onto the existing R-12 service valves AND are color-coded . . . or should be.
Considering that R-12 has been replaced by R-134a since the 1990s, there's no telling what gas is in the system. Could be residual R-12, "something else" of unknown origin, R-134a, etc. Which can lead to the distinct possibility that no a/c shop still had a R-12 recovery machine at this time. Which can bring the "contamination" issue I mentioned into greater focus.
Otherwise, use "line wrenches" on the fittings so you don't end up rounding-off the nuts. You'll also need some a/c-rated O-rings for reassembly, so keep track of what goes where. Plastic bags and a Sharpie work well for that. The securely cap/plug the existing lines so nothing gets inside of them while they are disconnected. You'll also need a new receiver/drier for the system, too.
Just a few things to watch for and be aware of,
CBODY67