All parts are brass, soldered together with lead solder. By observation, there are apparently different qualities of lead solder in the radiator shop industry. Reason I say that is that when there were radiator shops in every small town, those clean and re-solder jobs usually lasted about two years. Similar repair from a big-city high volume shop lasted several years longer. Solder cracks were the issue, rather than it breaking loose from poor adhesion.
Be sure to check the thinness of the flange where the crack is. It might be too thin to clean and "make solid" again. The color of the corrosion you found is from the (generally) green-colored antifreeze used in normal vehicles (meaning non-DexCool or any other special later-model coolant).
It would be best to get everything apart, as the heat you might apply to that area could melt the existing solder between the flange and the tank, causing more work than you might have desired. IF you clean one side, the other side will still be "dirty", so that would compromise any "in-place" repair you might make.
Just some thoughts,
CBODY67