More than likely someone back in the day was having trouble with the charging system and found that the alternator was not grounded properly through the brackets and added the wire. I always try to add a ground from the alternator to the block or the chassis when wiring a car to help make sure the system has everything it needs. This wire was never on the harness from the factory. It was added in. I would redo it and add one back in when redoing the harness under the hood. It is impossible to have too good or to many grounds!