The 22" shroud was used in AC, Trailer Tow and High Altitude / Hi Capacity Cooling options in 65. In 66 all that changed to 26" rads... but apparently they used up the 22" stuff as they got the 26" package going - one can still find 66 C bodies originally equipped with 22" rads and shrouds. It's also possible that shrouds were installed on 1966 C body cars when owners added dealer installed AC and trailer tow packages.
Regarding mounting, there should be two nuts captured in the slots roughly midway up the side straps of the rad to which specially formed brackets bolt to.
The ends of the two halves of the shroud nest together and bolt to the brackets.
I have two 65-66 22" C body specific rad shrouds and they are different from B body ones, and additionally, those brackets you have are most definitely NOT correct.
Both the correct C body shroud and brackets are hard to find... be sure they're correct as they won't allign to the fan properly otherwise.
Somewhere at home I may have some rad shroud images, but you need to give me some time.