Will it make any difference on charging when idling?
Low charging when idling is an ongoing problem with old Mopars... No doubt about it.
Here's what happens... Some guy will have that problem and do the "upgrade" to an isolated field alternator and an electronic regulator. Their problem stops, so they figure that's the way to fix it. They tell everyone on the forums, Facebook and all their buddies that the "dual field alternators is the cure".
What has really happened is they swapped out a low output alternator (bad diode etc.) and/or a bad regulator and/or bad wiring for new components... and what they aren't telling you is they now have a 60-100 amp alternator rather than the stock output version. They'll also do the "Mad" or "Nacho" ammeter bypass and declare they saved the world from another Chicago fire. No diagnosis of the original problem etc.
Now, there's nothing wrong with doing this "upgrade". People will argue all day that it is the way to go, but whatever.
It comes down to everything has to work. The alternator has to be spinning at the right speed, the regulator has to be turning the field off and on and making the alternator charge the battery. The wiring has to be good, including the connections at the firewall and at the ammeter, the battery cables tight and clean. A good battery etc.
IMHO, a good and sensible upgrade with a pre 1970 car is an electronic regulator. That's really all it needs. Then it's all preventive maintenance. Clean the battery cables and get rid of those problem causing "temporary" battery terminals that everyone loves to use. Clean the spade terminals at the firewall and slide under the dash and make sure the ammeter terminals are tight. This is the way my '65 Barracuda is set up.
My '70 Chrysler, on the other hand, has some added electronic load and for that, I've done the "Nacho" bypass... Of course, I didn't know that it had a name at the time, but here it is for those interested.
Some considerations about the charging and wiring upgrade and your worries about
Start adding stuff like EFI, electric fans, audio amplifiers etc. and that's another story.